Molecular clusters : a bridge to solid-state chemistry / Thomas Fehlner, Jean-François Halet, Jean-Yves Saillard.
Material type: TextSeries: Cambridge molecular science seriesPublisher: Cambridge : Cambridge University Press, 2007Description: 1 online resource (xi, 378 pages) : digital, PDF file(s)Content type:- text
- computer
- online resource
- 9780511628887 (ebook)
- 541.042 22
- QC173.4.M48 F44 2007
Title from publisher's bibliographic system (viewed on 05 Oct 2015).
Main-group clusters : geometric and electronic structure -- Transition-metal clusters : geometric and electronic structure -- Isolobal relationships between main-group and transition-metal fragments. Connections to organometallic chemistry -- Main-group-transition-metal clusters -- transition to the solid state -- From molecules to extended solids -- Inter-conversion of clusters and solid-state materials -- Appendix: Fundamental concepts : a concise review.
Clusters can be viewed as solids at the nano-scale, yet molecular cluster chemistry and solid state chemistry have traditionally been considered as separate topics. This treatment has made it conceptually difficult to appreciate commonalities of structure and bonding between the two. Using analogous models, this is the first book to form a connecting bridge. Although the focus is on clusters, sufficient attention is paid to solid-state compounds at each stage of the development to establish the interrelationship between the two topics. Comprehensive coverage of cluster types by composition, size and ligation, is provided, as is a synopsis of selected research. Written in an accessible style and highly illustrated to aid understanding, this book is suitable for researchers in inorganic chemistry, physical chemistry, materials science, and condensed matter physics.
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