TY - BOOK AU - Owens,Jeremy D. TI - Application of thallium isotopes: tracking marine oxygenation through manganese oxide burial T2 - Cambridge elements. Elements in geochemical tracers in Earth system science, 2515-7027 SN - 9781108688697 (ebook) AV - GC111.2 .O94 2019 U1 - 551.4601 23 PY - 2019/// CY - Cambridge PB - Cambridge University Press KW - Chemical oceanography KW - Oxygen N1 - Title from publisher's bibliographic system (viewed on 18 Dec 2019) N2 - Tracking initial ocean (de)oxygenation is critical to better constrain the coevolution of life and environment. Development of thallium isotopes has provided evidence to track the global manganese oxide burial which responds to early (de)oxygenation for short-term climate events. Modern oxic seawater thallium isotope values are recorded in organic-rich sediments deposited below an anoxic water column. An expansion of reducing conditions decrease manganese oxide burial and shifts the seawater thallium isotope composition more positive. Recent work documents that thallium isotopes are perturbed prior to carbon isotope excursions, suggesting ocean deoxygenation is a precursor for increased organic carbon burial. This Element provides an introduction to the application of thallium isotopes, case studies, and future directions UR - https://doi.org/10.1017/9781108688697 ER -