TY  - BOOK
AU  - Boyd,Richard H.
AU  - Smith,Grant D.
TI  - Polymer dynamics and relaxation
SN  - 9780511600319 (ebook)
AV  - QD381 .B69 2007
U1  - 547.7 22
PY  - 2007///
CY  - Cambridge
PB  - Cambridge University Press
KW  - Polymers
KW  - Structure
KW  - Molecular dynamics
N1  - Title from publisher's bibliographic system (viewed on 05 Oct 2015); Methodology -- Mechanical relaxation -- Dielectric relaxation -- NMR spectroscopy -- Dynamic neutron scattering -- Molecular dynamics (MD) simulations of amorphous polymers -- Amorphous polymers -- The primary transition region -- Secondary (subglass) relaxations -- The transition from melt to glass and its molecular basis -- Complex systems -- Semi-crystalline polymers -- Miscible polymer blends -- Appendix AI : the Rouse model -- Appendix AII : site models for localized relaxation
N2  - Polymers exhibit a range of physical characteristics, from rubber-like elasticity to the glassy state. These particular properties are controlled at the molecular level by the mobility of the structural constituents. Remarkable changes in mobility can be witnessed with temperature, over narrow, well defined regions, termed relaxation processes. This is an important, unique phenomenon controlling polymer transition behaviour and is described here at an introductory level. The important types of relaxation processes from amorphous to crystalline polymers and polymeric miscible blends are covered, in conjunction with the broad spectrum of experimental methods used to study them. In-depth discussion of molecular level interpretation, including atomistic level computer simulations and applications to molecular mechanism elucidation, are discussed. The result is a self-contained approach to polymeric interpretation suitable for researchers in materials science, physics and chemistry interested in the relaxation processes of polymeric systems
UR  - https://doi.org/10.1017/CBO9780511600319
ER  -